SYNTHESIS OF HYDROGENATED <i>MESO</i>-TETRAPYRIDYLPORPHYRINS WITH A CONTROLLED COMPOSITION
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Published:2023-01-01
Issue:1
Volume:508
Page:39-49
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ISSN:2686-9535
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Container-title:Доклады Российской академии наук. Химия, науки о материалах
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language:
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Short-container-title:Doklady Rossijskoj akademii nauk. Himiâ, nauki o materialah.
Author:
Lyubimtsev A. V.1, Semeikin A. S.1, Koifman M. O.1, Koifman O. I.1
Affiliation:
1. Ivanovo State University of Chemistry and Technology
Abstract
The work is devoted to the development of a method for obtaining a highly sensitive composition of a controlled composition containing cationic water-soluble 5,10,15,20-tetrakis(N-Me-pyridin-3-yl)chlorine and 5,10,15,20-tetrakis(N-Me-pyridin-3-yl)bacteriochlorin. The process of diimide reduction of 5,10,15,20-tetrakis(pyridin-3-yl)porphine in pyridine and in the absence of a solvent has been studied. It is shown that the reduction in the alloy significantly reduces the reaction time (from 12 to 1.5 h) and allows to obtain compositions with a yield of up to 90%.
Publisher
The Russian Academy of Sciences
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