Influence of self-heating on the kinetics of an exothermal reaction under isothermal conditions-Reference-Cited by-同舟云学术

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Influence of self-heating on the kinetics of an exothermal reaction under isothermal conditions

Published:2024-07-21 Issue:1 Volume:43 Page:47-51
ISSN:0207-401X
Container-title:Химическая физика
language:
Short-container-title:Himičeskaâ fizika

Author:

Korsunskiy B. L.¹²,Samoilenko N. G.¹

Affiliation:

1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry Russian Academy of Sciences

2. N.N. Semenov Federal Research Center for Chemical Physics Russian Academy of Sciences

Abstract

Estimates have been made showing that when an exothermal reaction proceeds in an isothermal medium (in a thermostat), self-heating occurs, the values of which are determined by the competition between the processes of heat input and heat removal. Relationships are obtained that make it possible to estimate the deviation of the observed values of the kinetic parameters from the true values and to reveal the influence of various parameters on these deviations.

Publisher

The Russian Academy of Sciences

Reference7 articles.

1. N. G. Samoilenko, A. A. Vinokurov, V. G. Abramov, A. G. Merzhanov, Zhurnal fiz. khimii 44(1), 39 (1970) [in Russian].

2. A. I. Serbinov, Doklady akademii nauk SSSR 129(3), 627 (1959) (in Russian).

3. A. I. Serbinov, Zhurnal fiz. khimii 33(12), 2641 (1970) (in Russian).

4. D. A. Frank-Kamenetskii, Diffusion and Heat Exchange in Chemical Kinetics (Nauka, Moscow, 1987; Springer, Heidelberg, 1995).

5. R. Meyer, J. Kohler, A. Homburg, Explosives. (Wiley-VCH, 2002. 474 p.).

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