Gas-Phase Conversion of Cation-Exchange Resin KU-2×8-M (M = Cs, Ni, Cu, Fe, Nd, U) in a Nitrating Atmosphere

Author:

Kulyukhin S. A.1,Gordeev A. V.1,Seliverstov A. F.1,Kazberova A. Yu.1,Kostikova G. V.1,Krasavina E. P.1,Nevolin Yu. M.1

Affiliation:

1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Abstract

A new approach to the destructive processing of the cation-exchange resin KU-2×8-M (M = Cs, Ni, Cu, Fe, Nd, U) based on its gas-phase treatment in a nitrating atmosphere with subsequent chemical treatment of the conversion products is considered. It is shown that exposure of KU-2×8-M samples (M = Cs, Ni, Cu, Fe, Nd, U) in an HNO3(vapour)-air atmosphere at temperatures of 403-443 K for 8 and 24 h followed by dissolution conversion products in 0.5 mol∙L-1 NaOH and ozonation of the resulting solutions allows e cient utilization of the KU-2×8-M resin (M = Cs, Ni, Cu, Fe, Nd, U).

Publisher

The Russian Academy of Sciences

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