Oxidation of the Styrene Epoxide–Sulfuric Acid Binary System in an Alcohol Solution-Reference-Cited by-同舟云学术

Oxidation of the Styrene Epoxide–Sulfuric Acid Binary System in an Alcohol Solution

Published:2023-04-15 Issue:2 Volume:63 Page:211-219
ISSN:0028-2421
Container-title:Нефтехимия
language:
Short-container-title:Neftehimiâ

Author:

Petrov L. V.¹,Spirin M. G.¹,Solyanikov V. M.¹

Affiliation:

1. Institute of Problems of Chemical Physics, Russian Academy of Sciences

Abstract

Oxygen uptake by the styrene epoxide (SE)–sulfuric acid (SA) binary system in a solution consisting of 90 vol % tert-butanol and 10 vol % chlorobenzene (BUC solvent) was studied. The equation for the reaction rate as a function of reactant concentrations and the Arrhenius equation for the effective oxidation rate constant are presented. Comparison of the results obtained with the data on oxidation in related binary systems SE–perchloric acid (PCA) and SE–p-toluenesulfonic acid (TSA) shows that the specific features of the oxidation of these systems are determined by the kind of the acid catalyst.

Publisher

The Russian Academy of Sciences

Reference58 articles.

1. Соляников В.М. Кинетика и механизм конкуренции гомо- и гетеролитических реакций в катализированном жидкофазном окислении углеводородов // Дисс.... докт. хим.наук. ОИХФ АН СССР. Черноголовка, Московской обл., 1985. 120 с.

2. Solyanikov V.M. Kinetics and mechanism of competition of homo- and heterolytic reactions in catalyzed liquid-phase oxidation of hydrocarbons // Diss. Doct. Chem. Sciences. OIHF of the USSR Academy of Sciences, Chernogolovka.

3. Imhausen A. Die Fettsäure - Synthese und ihre Bedeutung für die Sicherung der deutschen Fettversorgung // Kolloid - Zeitschrift. 1943. B. 103. S. 105-108. https://doi.org/10.1007/BF01502087

4. Langenbeck W., Pritzkow W. Untersuchungen über den Mechanismus der Paraffinoxydation, 2 Teil // Fette, Seifen, Anstrichmittel. 1953. V. 55. № 8. P. 506-511. https://doi.org/10.1002/lipi.19530550805

5. Wietzel G. Herstellung Synthetischer Fettsäuren durch Oxydation von Paraffinischen Kohlenwasserstoffen mit molekularen Sauerstoff // Chem. Eng. Sci. 1954. V. 3. Supplment 1. P. 17-30. IN1-IN4. https://doi.org/10.1016/S0009-2509(54)80003-0