Thermal Decomposition of Synthetic Cage Hydrocarbons and Their Mixtures-Reference-Cited by-同舟云学术

Thermal Decomposition of Synthetic Cage Hydrocarbons and Their Mixtures

Published:2023-04-15 Issue:2 Volume:63 Page:268-276
ISSN:0028-2421
Container-title:Нефтехимия
language:
Short-container-title:Neftehimiâ

Author:

Kazakov A. I.¹,Yanovskiy L. S.¹²³,Tomilov Yu. V.⁴,Molokanov A. A.¹³,Plishkin N. A.¹,Lempert D. B.¹,Varlamova N. I.¹

Affiliation:

1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

2. Moscow Aviation Institute (National Research University)

3. Moscow Power Engineering Institute (National Research University)

4. N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Abstract

The kinetics of thermal decomposition of cage hydrocarbons, specifically exo-tricyclo[5.2.1.02.6]decane (exo-TCD) and exo,endo-tetracyclo[5.3.1.02,6.08,10]undecane (TCU-1, a monocyclopropanated analog of exo-TCD), as well as their mixture (1 : 3 w/w) has been investigated. These compounds were compared in terms of thermal stability. The molar concentrations of the resultant gaseous products were determined experimentally. The equilibrium composition of the decomposition products was quantified, and the thermal effects of the thermal decomposition under thermodynamic and kinetic reaction control were identified.

Publisher

The Russian Academy of Sciences

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