Tetranuclear Heterometallic Iron(II)–Lithium Carboxylates Stabilized by N-Donor Ligands: Synthesis and Structure-Reference-Cited by-同舟云学术

Tetranuclear Heterometallic Iron(II)–Lithium Carboxylates Stabilized by N-Donor Ligands: Synthesis and Structure

Published:2023-08-01 Issue:8 Volume:49 Page:466-473
ISSN:0132-344X
Container-title:Координационная химия
language:
Short-container-title:Koordinacionnaâ himiâ

Author:

Yambulatov D. S.¹,Voronina Yu. K.¹,Nikolaevskii S. A.¹,Poddel’skii A. I.¹,Kiskin M. A.¹,Eremenko I. L.¹

Affiliation:

1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Abstract

The multicomponent chemical reactions of Fe(SO4)∙7H2O, Li(Рiv), K(Рiv) (Рiv is pivalate anion), and heterocyclic N-donor ligands (pyridine (Рy), 1,10-phenanthroline (Рhen)) in anhydrous acetonitrile under an inert atmosphere afford new heterometallic tetranuclear complexes [FeII2Li2(Рiv)6(Рy)4] (I) and [FeII2Li2(Рiv)6(Рhen)2] (II) in which all carboxylate anions act as bridging ligands. The molecular and crystal structures of the compounds are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2220576 (I) and 2220577 (II·2CH3CN). In the studied complexes, the iron(II) atoms exist in the distorted octahedral ligand environment.

Publisher

The Russian Academy of Sciences

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