Исследование возможности переноса насыщения в новом комплексе никеля(II) с 2,6-<i>бис</i>(пиразол-3-ил)пиридином-Reference-Cited by-同舟云学术

Исследование возможности переноса насыщения в новом комплексе никеля(II) с 2,6-<i>бис</i>(пиразол-3-ил)пиридином

Published:2023-12-01 Issue:12 Volume:49 Page:737-743
ISSN:0132-344X
Container-title:Координационная химия
language:
Short-container-title:Koordinacionnaâ himiâ

Author:

Aleshin D. Yu.¹,Nikovskii I. A.¹,Khakina E. A.¹²,Danshina A. A.¹³,Nelyubina Yu. V.¹⁴

Affiliation:

1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

2. Russia National Research University Higher School of Economics Moscow, Russia

3. Moscow Institute of Physics and Technology (National Research University), Dolgoprudnyi, Moscow oblast, Russia

4. Bauman State Technical University, Moscow, Russia

Abstract

By reacting the N,N'-disubstituted 2,6-bis(pyrazol-3-yl)pyridine ligand (L) with a divalent nickel salt, a new nickel(II) complex [Ni(L)(H2O)(THF)Cl]BPh4 was obtained (I), which was isolated in individual form and characterized by elemental analysis, mass spectrometry, NMR spectroscopy and X-ray diffraction (CCDC No. 2221412). According to NMR spectroscopy data in combination with the results of quantum chemical calculations, complex I in solution does not exhibit a saturation transfer effect.

Publisher

The Russian Academy of Sciences

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