Ligand Metathesis in Nickel(II) Complexation with closo-Decaborate Anion-Reference-Cited by-同舟云学术

Ligand Metathesis in Nickel(II) Complexation with closo-Decaborate Anion

Published:2023-06-01 Issue:6 Volume:49 Page:333-340
ISSN:0132-344X
Container-title:Координационная химия
language:
Short-container-title:Koordinacionnaâ himiâ

Author:

Avdeeva V. V.¹,Kubasov A. S.¹,Nikiforova S. E.¹,Goeva L. V.¹,Malinina E. A.¹,Kuznetsov N. T.¹

Affiliation:

1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

Abstract

Nickel(II) complexation with the closo-decaborate anion in water and acetonitrile is studied. Complexes [Ni(solv)6][B10H10] (solv = H2O (I) or CH3CN (II)) are isolated. The complexes are characterized by elemental analysis and IR spectroscopy. Complex [Ni(CH3CN)5(H2O)]0.75[Ni(CH3CN)4(H2O)2]0.25[B10H10]·0.5H2O (III) is isolated from an acetonitrile–water system. The structure of complex III is solved by X-ray diffraction (XRD) (CIF file CCDС no. 2224702). A mechanism of ligand metathesis in the complexation of nickel(II) is proposed.

Publisher

The Russian Academy of Sciences

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