Trimethylammonium dichloro-hexachlorotellurate(IV): crystal structure and features of non-covalent interactions of Cl···Cl-Reference-Cited by-同舟云学术

Trimethylammonium dichloro-hexachlorotellurate(IV): crystal structure and features of non-covalent interactions of Cl···Cl

Published:2023-12-01 Issue:12 Volume:49 Page:767-771
ISSN:0132-344X
Container-title:Координационная химия
language:
Short-container-title:Koordinacionnaâ himiâ

Author:

Usoltsev A. N.¹,Sonina A. A.²,Korobeinikov N. A.¹³,Adonin S. A.¹⁴

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

2. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

3. Novosibirsk State University, Novosibirsk, Russia

4. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Abstract

By the reaction of tellurium(IV) oxide with trimethylammonium chloride in the presence of chlorine gas in concentrated hydrochloric acid, supramolecular dichloro-hexachlorotellurate (Me3NH)2{[TeCl6](Cl2)} (I) was obtained, the structure of which was determined by X-ray diffraction. Based on elemental and X-ray phase analysis data, a conclusion was made about the limited stability of the resulting compound. The features of non-covalent Cl···Cl interactions in the crystal structure of this compound were studied by Raman spectroscopy (Raman).

Publisher

The Russian Academy of Sciences

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