A Surprising Example of Crystal Structure Retention for 3,5-Di-(tert-butyl)-2-hydroxyazobenzene Ligand during the Formation of Ni(II) and Pd(II) Complexes-Reference-Cited by-同舟云学术

A Surprising Example of Crystal Structure Retention for 3,5-Di-(tert-butyl)-2-hydroxyazobenzene Ligand during the Formation of Ni(II) and Pd(II) Complexes

Published:2023-05-01 Issue:5 Volume:49 Page:308-314
ISSN:0132-344X
Container-title:Координационная химия
language:
Short-container-title:Koordinacionnaâ himiâ

Author:

Aldoshin S. M.¹,Tkachev V. V.¹,Utenyshev A. N.¹,Bozhenko K. V.¹

Affiliation:

1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

Abstract

The structures of 3,5-di-(tert-butyl)-2-hydroxyazobenzene (L) in the free state and in complexes with Ni2+ (I) and Pd2+ (II) cations are studied by X-ray diffraction (XRD). The same space group R3¯с with close unit cell parameters, the same crystal structure motif, and unusual conformations of the cupola-shaped coordination polyhedra of complexes I and II are revealed by XRD for ligand L. In complexes I and II based on this compound as the ligand, the coordinating atoms form trans-planar coordination nodes.

Publisher

The Russian Academy of Sciences

Reference16 articles.

1. Коган В.А., Харабаев Н.Н., Осипов О.А., Юрченко Э.Н. // Журн. общ. химии. 1975. № 45. С. 362.

2. Коган В.А., Харабаев Н.Н., Осипов О.А., Кочин С.Г. // Журн. структур. химии. 1981. Т. 22. № 1. С. 126.

3. Дьяченко О.А., Атовмян Л.О., Алдошин С.М., Ткачев В.В. // Журн. структур. химии. 1978. Т. 19. № 5. С. 829.

4. Kogan V.A., Kochin S.G., Antsyshkina A.S. et al. // Mendeleev Commun. 1997. V. 7. № 6. C. 239.

5. Алдошин C.М., Алексеенко В.А., Атовмян Л.О. и др. // Коорд. химия. 1975. Т. 10. С. 1075.