Structure and Thermal Characteristics of Bis(triethylammonium)-tetrakis(3,5-dinitro-2-pyridonato)cobalt(II)-Reference-Cited by-同舟云学术

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Structure and Thermal Characteristics of Bis(triethylammonium)-tetrakis(3,5-dinitro-2-pyridonato)cobalt(II)

Published:2023-05-01 Issue:5 Volume:49 Page:290-297
ISSN:0132-344X
Container-title:Координационная химия
language:
Short-container-title:Koordinacionnaâ himiâ

Author:

Nikiforova M. E.¹,Kayumova D. B.¹,Malkerova I. P.¹,Alikhanyan A. S.¹,Kiskin M. A.¹,Sidorov A. A.¹,Khoroshilov A. V.¹,Dalinger I. L.²,Starosotnikov A. M.²,Bastrakov M. A.²,Eremenko I. L.¹³

Affiliation:

1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

2. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia

3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

Abstract

The ionic compound [Co(OC5H2N(NO2)2)4]((C2H5)3NH)2 (I) was synthesized by the reaction of CoCl2·6H2O with 2-hydroxy-3,5-dinitropyridine in acetonitrile in the presence of triethylamine as a deprotonating agent. The structure of compound I was studied by X-ray diffraction (CCDC no. 2196071) and thermodynamic characteristics of I were determined.

Publisher

The Russian Academy of Sciences

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