Specific Features of the Oxidative Addition of Triarylantimony to Dihydroxybenzoic Acids-Reference-Cited by-同舟云学术

Specific Features of the Oxidative Addition of Triarylantimony to Dihydroxybenzoic Acids

Published:2023-03-01 Issue:3 Volume:49 Page:183-192
ISSN:0132-344X
Container-title:Координационная химия
language:
Short-container-title:Koordinacionnaâ himiâ

Author:

Sharutin V. V.¹,Sharutina O. K.¹,Belov V. V.¹

Affiliation:

1. South Ural State University (National Research University), Chelyabinsk, Russia

Abstract

Tris(2-methoxyphenyl)antimony and tris(3-fluorophenyl)antimony react with 2,3-dihydroxybenzoic and 3,4-dihydroxybenzoic acids in the presence of tert-butyl hydroperoxide to form carboxycatecholato-О,О'-triarylantimony. Under similar conditions, tris(4-fluorophenyl)antimony reacts with 2,3-dihydroxybenzoic acid to form tris(4-fluorophenyl)antimony dicarboxylate. Structural features of the reaction products are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2126358 (I), 2124252 (II·H2O·Et2O), 2121839 (III·0.5С6Н6), and 2131083 (IV·2.5С6Н6).

Publisher

The Russian Academy of Sciences

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