Competitive effects of substitutions in La<sub>1 – <i>x</i></sub>Sr<sub><i>x</i></sub>Mn<sub>0.9</sub>(Mg<sub><i>y</i></sub>Ge<sub><i>z</i></sub>)<sub>0.1</sub>O<sub>3 + γ</sub> system

Author:

Badelin A. G.1,Derzhavin I. M.1,Karpasyuk V. K.1,Estemirova S. Kh.12

Affiliation:

1. Astrakhan State University

2. Institute for Metallurgy of the Ural Branch of the Russian Academy of Sciences

Abstract

Structural, magnetic, and electrical characteristics of La1 – xSrxMn0.90(Mg0.5Ge0.5)0.10O3 + γ (0.15 x 0.30, γ = 0, γ 0) and La0.91Sr0.09Mn0.90Mg0.10O3, La0.71Sr0.29Mn0.90Ge0.10O3 manganites are investigated and compared. Comparison of the properties of manganites having identical summary concentrations of substituents for manganese and equivalent concentrations of Mn4+, Mn3+ ions revealed several competing effects caused by Sr2+(4p6), Mg2+(2p6), Ge4+(3d10) ions and oxygen.

Publisher

The Russian Academy of Sciences

Reference21 articles.

1. Belich N., Udalova N., Semenova A. et al. // Front. Chem. 2020. V. 8. Art. No. 550625.

2. Бебенин Н.Г., Зайнуллина Р.И., Устинов В.В. // УФН. 2018. Т. 188. № 8. С. 801

3. Bebenin N.G., Zainullina R.I., Ustinov V.V. // Phys. Usp. 2018. V. 61. No. 8. P. 719.

4. Presniakov I.A., Rusakov V.S., Gubaidulina T.V. et al. // Phys. Rev. B. 2007. V. 76. No. 21. Art. No. 214407.

5. Karpasyuk V.K., Badelin A.G., Derzhavin I.M. et al. // J. Magn. Magn. Mater. 2019. V. 476. P. 371.

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