Features of Cl K-edge XANES spectra of metal transition complexes {MCl6}n– (M = Rh, Pd, Re, Os, Ir, Pt)-Reference-Cited by-同舟云学术

Features of Cl K-edge XANES spectra of metal transition complexes {MCl6}n– (M = Rh, Pd, Re, Os, Ir, Pt)

Published:2023-05-01 Issue:5 Volume:87 Page:738-746
ISSN:0367-6765
Container-title:Известия Российской академии наук. Серия физическая
language:
Short-container-title:Izvestiâ Akademii nauk SSSR. Seriâ fizičeskaâ

Author:

Fedorenko A. D.¹,Asanov I. P.¹,Asanova T. I.¹,Vasilchenko D. B.¹,Nikolenko A. D.²³⁴,Piminov P. A.³⁴,Karyukina K. Yu.³⁴

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

2. Federal Research Center Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences”

3. Budker Institute of Nuclear Physics of the Siberian Branch of the Russian Academy of Sciences

4. Synchrotron Radiation Facility – Siberian Circular Photon Source “SKIF”, Boreskov Institute of Catalysis of Siberian Branch of the Russian Academy of Sciences

Abstract

Cl K-edges of a set of chlorides of 4d- and 5d-transition metals {MCl6}n– (M = Rh, Pd, Re, Os, Ir, Pt) were obtained using the “Cosmos” station of the VEPP-4 synchrotron. The combined use of experimental X-ray and theoretical methods made it possible to determine the magnitude of the spin-orbit interaction (SOC) depending on the transition metal. The features of the Cl K-edge are analyzed with and without SOC, as well as stretched and compressed complexes.

Publisher

The Russian Academy of Sciences

Reference61 articles.

1. Стрельцов С.В., Хомский Д.И. // УФН. 2017. Т. 187. № 11. С. 1205

2. Streltsov S.V., Khomskii D.I. // Phys. Usp. 2017. V. 60. No. 11. P. 1121.

3. Streltsov S.V., Khomskii D.I. // Phys. Rev. X. 2020. V. 10. No. 3. Art. No. 031043.

4. Takayama T., Chaloupka J., Smerald A. et al. // J. Phys. Soc. Japan. 2021. V. 90. No. 6. Art. No. 062001.

5. Kim B.J., Ohsumi H., Komesu T. et al. // Science. 2009. V. 323. No. 5919. P. 1329.