Affiliation:
1. MIREA – Russian Technological University (Lomonosov Institute of Fine Chemical Technologies)
Abstract
The kinetics of the CO oxidation to CO2 in the PdBr2–CuBr2–THF–H2O system was studied outside the coupled process of cyclohexene hydrocarboxylation. The kinetic model was obtained and the reaction mechanism was proposed. The influence of the hydrocarboxylation reaction of alkenes on the CO oxidation to CO2 was established in the coupled process which has been previously studied.
Publisher
The Russian Academy of Sciences
Reference27 articles.
1. Темкин О.Н. Гомогенный металлокомплексный катализ. Кинетические аспекты. М.: Академкнига, 2008. 918 с.
2. Брук Л.Г., Темкин О.Н. // Кинетика и катализ. 2016. Т. 57. № 3. С. 275. (Bruk L.G., Temkin O.N. // Kinet. Catal. 2016. V. 57. № 3. P. 277.)
3. Брук Л.Г., Ошанина И.В., Городский С.Н., Темкин О.Н. // Рос. хим. журн. 2006. Т. 50. № 4. С. 103.
4. Абдуллаева А.С., Тимашова Е.А., Букина Е.Ю., Ошанина И.В., Брук Л.Г., Темкин О.Н. // Вестн. МИТХТ. 2008. Т. 3. № 4. С. 63.
5. Брук Л.Г., Темкин О.Н., Абдуллаева А.С., Тимашова Е.А., Букина Е.Ю., Одинцов К.Ю., Ошанина И.В. // Кинетика и катализ. 2010. Т. 51. № 5. С. 702. (Bruk L.G., Temkin O.N., Abdullaeva A.S., Timashova E.A., Bukina E.Yu., Odintsov K.Yu., Oshanina I.V. // Kinet. Catal. 2010. V. 51. № 5. P. 678.)