Effect of the Hydride and Carbide Phases of Palladium Nanoparticles on the Vibration Frequencies of Adsorbed Surface Molecules-Reference-Cited by-同舟云学术

Effect of the Hydride and Carbide Phases of Palladium Nanoparticles on the Vibration Frequencies of Adsorbed Surface Molecules

Published:2023-03-01 Issue:2 Volume:64 Page:216-226
ISSN:0453-8811
Container-title:Кинетика и катализ
language:
Short-container-title:Kinetika i kataliz

Author:

Usoltsev О. А.¹,Protsenko B. О.¹,Pnevskaya А. Yu.¹,Bulgakov А. N.¹,Bugaev А. L.¹

Affiliation:

1. The Smart Materials Research Institute of the Southern Federal University

Abstract

Palladium-based materials, including nanoparticles, are widely used in the petrochemical, pharmaceutical, automotive, and other industries. The hydride, carbide, and oxide phases of palladium formed during the hydrogenation or oxidation reactions of hydrocarbons significantly affect the catalytic properties of the catalyst. Based on theoretical calculations performed by the density functional theory (DFT) method, the effect of Pd–Pd interatomic distances and the presence of carbon atoms occupying octahedral voids in the fcc lattice of palladium on the vibrational frequencies of adsorbed hydrocarbons represented by ethylidene is shown. Theoretical research is supported by experimental data of infrared (IR) diffuse reflectance spectroscopy (DRIFTS) collected in situ during the formation of carbide and hydride phases of palladium in commercial Pd/Al2O3 nanocatalysts under the influence of ethylene and hydrogen. The proposed approach can be used to develop new methods for IR spectra analysis leading to the quantitative diagnostics of structural changes in palladium during various catalytic reactions in the in situ mode.

Publisher

The Russian Academy of Sciences

Reference61 articles.

1. Bond G., Dowden D., Mackenzie N. The selective hydrogenation of acetylene // Trans. Faraday Soc. 1958. V. 54. P. 1537.

2. Borodziński A., Bond G.C. Selective hydrogenation of ethyne in ethene-rich streams on palladium catalysts, Part 2: Steady-state kinetics and effects of palladium particle size, carbon monoxide, and promoters // Catal. Rev. 2008. V. 50. № 3. P. 379.

3. Teschner D., Borsodi J., Kis Z., Szentmiklosi L., Revay Z., Knop-Gericke A., Schlogl R., Torres D., Sautet P. Role of Hydrogen Species in Palladium-Catalyzed Alkyne Hydrogenation // J. Phys. Chem. C. 2010. V. 114. № 5. P. 2293.

4. Teschner D., Borsodi J., Wootsch A., Révay Z., Hävecker M., Knop-Gericke A., Jackson S.D., Schlögl R. The Roles of Subsurface Carbonband Hydrogen in Palladium-Catalyzed Alkyne Hydrogenation // Science. 2008. V. 320. № 5872. P. 86.

5. Borodziński A., Bond G.C. Selective hydrogenation of ethyne in ethene-rich streams on palladium catalysts. Part 1. Effect of changes to the catalyst during reaction // Catal. Rev. 2006. V. 48. № 2. P. 91.