Transport Properties of In3+- and Y3+-Doped Hexagonal Perovskite Ba5In2Al2ZrO13
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Published:2023-03-01
Issue:3
Volume:59
Page:143-157
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ISSN:0424-8570
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Container-title:Электрохимия
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language:
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Short-container-title:Èlektrohimiâ
Author:
Andreev R. D.12, Anokhina I. A.12, Korona D. V.12, Gilev A. R.1, Animitsa I, E.1
Affiliation:
1. Ural Federal University named after the First President of Russia B.N. Yeltsin 2. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences
Abstract
A complex oxide Ba5In1.9Y0.1Al2ZrO13 with hexagonal perovskite structure (a = 5.971(4) Å, с = 24.012(1) Å) is prepared for the first time. The phase is found to dissociative-absorb water from gas phase, the degree of hydration being as high as 0.39 mol Н2О. It was found by using IR-spectroscopy that protons are present therein as energetically nonequivalent ОН–-groups involved in hydrogen bonds of diverse strength. Isovalent yttrium-doping of the Ba5In2Al2ZrO13 phase is shown not to lead to any valuable change in the oxygen-ion-conductivity as compared with the Ba5In2.1Al2Zr0.9O12.95 acceptor doping that allows increasing the oxygen-ion-conductivity by a factor of 1.3. Both types of doping lead to increase in the proton conductivity and, as a corollary to this, an increase in the proton concentration. For these phases the degree of hydration depends on the cell parameters, hence, is determined by space availability for ОН–-groups in the barium coordination. Proton transport dominates in the Ba5In2Al2ZrO13, Ba5In2.1Al2Zr0.9O12.95, and Ba5In1.9Y0.1Al2ZrO13 phases below 600оС in humid atmosphere (pH2О = 1.92 × 10–2 atm).
Publisher
The Russian Academy of Sciences
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