FEATURES OF THE ELECTROCHEMICAL BEHAVIOR OF CHLOROPHENOXY SUBSTITUTED COBALT AND COPPER PHTHALOCYANINATES IN NON-AQUEOUS MEDIA
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Published:2023-09-01
Issue:9
Volume:59
Page:495-500
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ISSN:0424-8570
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Container-title:Электрохимия
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language:
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Short-container-title:Èlektrohimiâ
Author:
Kovanova M. A.1, Tikhomirova T. V.1, Sakhapov I. F.2, Gafurov Z. N.2, Yakhvarov D. G.2, Vashurin A. S.1
Affiliation:
1. Ivanovo State University of Chemistry and Technology 2. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences
Abstract
The electrochemical behavior of tetra-4-[4-(2,4,5-trichlorophenoxy)]phthalocyaninates of cobalt(II) (CoPc) and copper(II) (CuPc) in N,N-dimethylformamide 0.1 M nBu4NBF4 was studied by cyclic voltammetry. It has been experimentally established that both metal complexes are capable of irreversible reduction. In the reverse part of the CV curve for CoPc, an oxidation peak is observed, which is absent during anodic scanning, and corresponds to the cathodic reaction product. The metal complexes themselves do not oxidize under the conditions.
Publisher
The Russian Academy of Sciences
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