Infrared-spectroscopy analysis of zinc phosphate and nickel and manganese modified zinc phosphate coatings on electrogalvanized steel

Author:

Fernandes Kirlene Salgado,Alvarenga Evandro de Azevedo,Brandão Paulo Roberto Gomes,Lins Vanessa de Freitas Cunha

Abstract

Hopeite-type phosphate coatings in which zinc is partially replaced by other metals like manganese and nickel are of great interest for the automotive and home appliance industries. Such industries use phosphate conversion coatings on galvanized steels in association with cataphoretic electropainting. Zinc phosphates modified with manganese and nickel are isomorphic with the hopeite, and the phase identification using X-ray diffraction is difficult. In this paper, the phosphate coatings are identified using the Fourier transform infrared spectroscopy (FTIR).

Publisher

FapUNIFESP (SciELO)

Subject

Economic Geology,Geochemistry and Petrology,Geology,Waste Management and Disposal,General Materials Science

Reference11 articles.

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3. Characterization of the phosphate coating in galvanized steels by Fourier Transform infrared spectroscopy;FERNANDES K.S.,2002

4. An infrared and Raman spectroscopic study of natural zinc phosphates;FROST R.L.;Spectrochimica Acta Part A,2004

5. IR-Spectroscopic investigations on phosphated galvanized steel;MOLT K.;Microchimica Acta,1994

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