Stability of cubic phase in nanocrystalline ZrO2

Author:

Chatterjee A.,Pradhan S.K.,Datta A.,De M.,Chakravorty D.

Abstract

Stable cubic ZrO2 up to a temperature of 1173 K has been synthesized by a chemical precipitation technique. Such a stability appears to be driven by particle size. The critical value below which cubic ZrO2 has been found to be stable is 17 nm. The x-ray diffraction pattern of such ultrafine cubic particles is similar to that obtained by stabilization of ZrO2 by the addition of 20 mole % CaO.

Publisher

Springer Science and Business Media LLC

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

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