Contribution of electrolysis current to growth of SrTiO3 thin film by the hydrothermal-electrochemical method

Author:

Kajiyoshi Koji,Tomono Kunisaburo,Hamaji Yukio,Kasanami Toru,Yoshimura Masahiro

Abstract

The electrolysis treatment of the hydrothermal-electrochemical method has been modified so that it permits SrTiO3 thin films to be grown on Ti electrodes being oxidized anodically in Sr(OH)2 solutions far beyond a thickness limit of several tens of nanometers hitherto attained. The relation between the total current passed through the Ti anode and the amount of the resulting SrTiO3 film was analyzed on the basis of a reaction model that interprets the anodic current to be compensated with electrons generated partly by oxidation of Ti and partly by decomposition of H2O. Current efficiency for the film growth was estimated to be in the range from 0.8 to 3% depending on the Ti electrode potential.

Publisher

Springer Science and Business Media LLC

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference19 articles.

1. 14 Powder Diffraction File, No. 35-734 (Joint Committee on Powder Diffraction Standards, International Center for Diffraction Data, Swarthmore, PA, 1985).

2. ELECTROMOTIVE FORCE MEASUREMENTS IN AQUEOUS SOLUTIONS AT ELEVATED TEMPERATURES. II. THERMODYNAMIC PROPERTIES OF HYDROCHLORIC ACID1

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