Parametric Effects of Glass Reaction Under Unsaturated Conditions

Author:

Bates John K.,Gerding Thomas J.,Woodland Alan B.

Abstract

ABSTRACTEventual liquid water contact of high-level waste glass stored under the unsaturated conditions anticipated at the Yucca Mountain site will be by slow intrusion of water into a breached container/canister assembly. The water flow patterns under these unsaturated conditions will vary, and the Unsaturated Test method has been developed by the YMP to study glass reaction. The results from seven different sets of tests done to investigate the effect of systematically varying parameters such as composition and degree of sensitization of 304L stainless steel, water input volume, and the interval of water contact are discussed. Glass reaction has been monitored over a period of five years, and the parametric effects can result in up to a ten-fold variance in the degree of glass reaction.

Publisher

Springer Science and Business Media LLC

Subject

General Engineering

Reference5 articles.

1. 3. Bourcier W. L. , “Geochemical Modeling of Radioactive Waste Glass”, Lawrence Livermore National Laboratory report UCRL-57012, in press.

2. 5. Bates J. K. , Argonne National Laboratory, unpublished results (1989).

3. NNWSI Phase II materials interaction test procedure and preliminary results

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