Control of nanosilver sintering attained through organic binder burnout

Abstract

Control of the low-temperature sintering of nanosilver particles was attained by dispersing and stabilizing nanosilver particles into a paste form using the selected organic binder systems. As demonstrated by scanning electron microscopy (SEM) and thermogravimetric analysis (TGA), with the existing binder systems, undesirable premature coalescence of nanosilver particles was prevented and the metastable structure was retained until the binder burned out at relatively higher temperatures. Enhanced densification was achieved upon the binder burnout because at the relatively higher temperatures the densification mechanisms, e.g., grain-boundary or lattice diffusion, become more dominant. We propose that the onset of sintering, extent of densification, and final grain size can be controlled by either the size of the initial nanosilver particles or the binder systems with different burnout characteristics.