Nucleation and growth rate influence on microstructure and critical currents of TFA-YBa2Cu3O7 under low-pressure conditions

Abstract

The effects of variable conversion parameters on the microstructure and critical currents of TFA-derived YBa2Cu3O7 (YBCO) films annealed under low-pressure conditions were investigated, accompanied by the analysis of their relationship with the nucleation process and the growth rate. It is found that non-c-axis oriented YBCO grains are formed under high supersaturation conditions, i.e., by increasing oxygen pressure, water pressure, or temperature. The optimal PH2O–PO2 window for preparation of completely c-axis oriented YBCO films expands as the total pressure rises from 50 to 100 mbar due to the decrease of supersaturation at enhanced total pressure; the corresponding maximum growth rate is only slightly increased up to 0.6 nm/s. Additionally, it is shown that the gas flow needs to be high enough to avoid random nucleation of YBCO grains. A single gas-flow–water-pressure diagram, showing simultaneously the film-growth rate, allows visualizing the cross-linked influence of processing parameters to achieve c-axis oriented YBCO films with Jc above 1 MA/cm2 in one single growth step.