Generation of Volatile Organic Compounds by Alpha Particle Degradation of Wipp Plastic and Rubber Material

Author:

Reed Donald T.,Molecke Martin A.

Abstract

ABSTRACTThe generation of volatile organic compounds (VOCs), hydrogen, and carbon oxides due to alpha particle irradiation of polyethylene, polyvinylchloride, hypalon, and neoprene, is being investigated. A wide diversity of VOCs was found including alkenes, alkanes, alcohols, ketones, benzene derivatives, and nitro compounds. Their yields however, were quite low. The relative amounts of these compounds depended on the material, atmosphere present, and the absorbed dose. This investigation will help evaluate the effect of ionizing radiation on the long-term performance assessment and regulatory compliance issues related to the Waste Isolation Pilot Plant (WIPP).

Publisher

Springer Science and Business Media LLC

Subject

General Engineering

Reference9 articles.

1. 9 Brush L.H. , Molecke M.A. , Westerman R.E. , Francis A.J. , Gillow J.B. , Vreeland R.H. and Reed D.T. , “ Laboratory Studies of Gas Generation for the Waste Isolation Pilot Plant,” Proceedings of Symposium on Scientific Basis for Nuclear Waste Management XVI, 294 (1992) 335–342.

2. Gas Generation from Organic Transuranic Wastes. I. Alpha Radiolysis at Atmospheric Pressure

3. 2A.R. Lappin and R. Hunter, Eds., “Systems Analysis, Long-Term Radionuclide Transport, and Dose Assessments, Waste Isolation Pilot Plant (WIPP), Southeastern New Mexico”. Sandia National Laboratories Report SAND89-0462 (1989).

4. Reactive Intermediates in the Radiation Chemistry of Polyethylene

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