Synthesis of Mn2+ Doped CdS Nanocrystals Embedded in a Sol-Gel Silica Matrix: Characterization of the Luminescence Activator

Author:

Counio G.,Esnouf S.,Gacoin T.,Barboux P.,Hofstaetter A.,Boilot J.-P.

Abstract

AbstractMn2+-doped CdS nanocrystals (1.2 to 2.4 nm in diameter) embedded in organic-inorganic silica xerogels have been synthesized. Extensive studies (EXAFS, ESR and ENDOR) allow us to localize the ions responsible for the bright luminescence observed in such materials (quantum yield of 7%). The average number of Mn2+ per nanocrystal is in the 0.2–0.8 range, and the emission arises from an energy transfer from surface trapped carriers to Mn2+ ions.

Publisher

Springer Science and Business Media LLC

Subject

General Engineering

Reference12 articles.

1. Sensitized Electroluminescent Response

2. 11 Counio G. , Esnouf S. , Gacoin T. and Boilot J.-P. , accepted in J. Phys. Chem.

3. Quantum crystallites and nonlinear optics

4. Optical properties of Mn-doped CdS nanocrystals

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1. Tweaking the band gap and photoluminescence of CsPbI3 perovskite by Mn alloying;Photonics for Solar Energy Systems IX;2022-05-24

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