Polymer-Dispersed Liquid Crystals: Boojums at Work

Abstract

The idea of dispersing micron-size birefringent particles in a polymer to selectively scatter light is not new. In the 1930s Land patented a light polarizing material in which small, oriented solid crystallites were suspended in a clear polymer. The polymer material was selected so that its refractive index matched one of the principal refractive indices of the crystallites while the other did not. The resuit was a light polarizer tha t would pass one component of polarized light but scatter the other component out of the beam path.This idea was substantially expanded by the introduction of liquid crystals as the birefringent material. The orientation of the particles (in this case droplets), and hence the refractive index match and the scattering, could be controlled by an electric field. Such a material could be used as a light shutter for either unpolarized or polarized light. In the mid-1970s this basic concept was applied by Hilsum, but having no way to disperse droplets of liquid crystals in a polymer, he did the opposite and put optically isotropic solid particles in the birefringent liquid crystal.Although Hilsum demonstrated the concept, no commercial device was produced, probably because the shutter contrast was limited. Since then several ways have been found to disperse droplets in a polymer: filling the pores of a microfilter; emulsifying the liquid crystal in a water soluble polymer; and using phase separation methods to create a dispersion of droplets in non-aqueous polymer materials.