From the de Broglie to Visible Wavelengths: Manipulating Electrons and Photons With Colloids

Abstract

Because of their size and ability to selforganize, colloidal particles are ideal building blocks for the creation of three-dimensional (3D) structures that can have feature sizes of the order of the wavelength of electrons, photons, or both. This article is too short to provide an extensive literature survey but instead will give some illustrative examples, based on work of the author and co-workers, of how specially developed core-shell particles might be organized on a 3D lattice. These examples are only intended to give an impression of how colloidal-particle systems can be used in the design of new materials with interesting photonic properties.Generally particles are considered colloidal if their size is between several nm and several μm. This range is more or less defined by the importance of Brownian motion—that is, the irregular, overdamped, random displacements the particles make as a result of the not completely averaged-out bombardment of solvent (or gas) molecules. Consequently the lower size range is determined by the size of the solvent molecules. Compared to the particle size, the solvent molecules need to be so small that the time scales of the solvent molecules and particles are so far apart that the solvent molecules can be “integrated out” in a description of the particles. If such a description holds, the solvent can be approximated well by a continuum. The upper size limit is determined by the size at which external fields, like gravity, start to overshadow the effects of Brownian motion.