The Role of Chemical Additives in Sol-Gel Processing

Author:

Hench L. L.,Orcel G.,Nogues J. L.

Abstract

ABSTRACTThe effect of various concentrations of formamide with and without acid catalysis on TMOS derived silica sol and gel structures and physical properties is described using a quantitative structural model. The model is based upon 29Si NMR, SAXS, Raman and FTIR spectroscopy, and an acid solubility test. Changes in chemical reactions during drying due to formamide are presented using FTIR, DSC and TGA data.

Publisher

Springer Science and Business Media LLC

Subject

General Engineering

Reference13 articles.

1. 6. Orcel G. , Phalippou J. and Hench L.L. , submitted to J. Non-Cryst. Solids.

2. 3. Orcel G. , Gould R.W. , and Hench L.L. , presented at the 1986 Spring Meeting, Palo Alto, CA 1986 (these proceedings).

3. 10. Hench L.L. and Orcel G. , presented at the Third International Workshop on Glasses and Class-Ceramics from Gels, Montpellier, France, 1985 (in press).

4. Effect of formamide additive on the chemistry of silica sol-gels

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