Author:
Vanderah David J.,Nielsen A. T.,Hollins R. A.,Baum Chris
Abstract
ABSTRACTRecently we have synthesized several new aryl compounds substituted with two or more trinitromethyl groups. Vacuum pyrolysis of one of these—±,±,±,±’,±’,±’-hexanitro-p-xylene (p-HNX)—gave the title compound via 1,6-elimination of N2O4. Structural assignment of TNQ is based on spectral evidence (UV, 1H NMR and mass spectrometry) and conversion to the known l,4-bis(bromodinitromethyl)benzene. Evidence for the formation of the TNQ radical anion has been obtained.
Publisher
Springer Science and Business Media LLC
Reference11 articles.
1. Control of the Electronic Structure of Organic Conductors as Exemplified by[NMP][TCNQ] Charge-Transfer Complexes
2. 10. This material has not been fully characterized.
3. 5. Novikov S.S. , Khmel’netskii L.I. , Novikova T.S. , Lebedev O.V. , and Epishina L.V. , Ibid, 6, 619 (1970).
4. Preparation of p-bis(dinitromethyl)benzene
5. 2. Khmel’nitskii K.I. , Novikov S.S. , and Lebedev O.V. , Ibid, 1873 (1960).
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