Effect Of Moisture On The Physical Properties Of Polyimide Films

Author:

Subramanian Rajeevi,Pottiger Michael T.,Morris Jacqueline H.,Curilla Joseph P.

Abstract

ABSTRACTMoisture absorption and its effect on electrical properties were measured for several polyimides. A Quartz Crystal Microbalance (QCM) was used to investigate the moisture absorption in BPDA/PPD, PMDA/ODA, and BTDA//ODA/MPD polyimides. The steady-state moisture uptake in polyimides as a function of relative humidity (RH) was determined by exposing film samples to successively higher RH values ranging from 10 to 85% at 25°C. The isothermal moisture absorption as a function of percent RH was found to be nearly linear for all of the polyimides studied. The effect of moisture on the electrical properties of a BPDA/PPD polyimide was also investigated. The relative dielectric constant at 25 °C was found to be a linear function of the moisture absorbed.

Publisher

Springer Science and Business Media LLC

Subject

General Engineering

Reference15 articles.

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2. 2. Pottiger M. T. , Subramanian R. , and Ward M. D. , “Moisture Absorption in Thin Polymer Films Using a Quartz Crystal Microbalance”, presented at the Second Du Pont Symposium on High Density Interconnect Technology, Wilmington, DE, November 4–5, 1989.

3. Experimental aspects of use of the quartz crystal microbalance in solution

4. Dielectric relaxation and deuteron NMR of water in polyimide films

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