Possible Formation of H-type Aggregates in H2TPyP/PMMA Guest Host Films

Author:

Mota Wesley da Silva,Melo Wanessa Canedo,Nunes Luiz Antônio de Oliveira,Machado Antônio Eduardo da Hora,Batista Alzir Azevedo,Guedes Ilde,Barbosa Newton Martins

Abstract

AbstractIn this work we have employed UV-Vis absorbance and excitation techniques in addition to quantum chemical calculations to investigate the probable formation of H-type aggregates of zero charged aryl substituted porphyrin in a guest- host solid state structure. The films were factored via casting technique mixing free-base tetrapyridyl porphyrins (H2TPyP) and polymethilmethacrilate polymer (PMMA) chlorophorm solutions. A pathway for the possible formation of H-type aggregate is suggested.

Publisher

Springer Science and Business Media LLC

Subject

General Engineering

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