Fixation of high Level Solid Waste (HLSW) in a TiO2 Base Ceramic Matrix Provided with an Integrated Overpack

Author:

Bauer Christof,Ondracek Gerhard

Abstract

In the past years a lot of research work has been done in several countries to find a waste form capable of accommodating the wide variety of elements present in commercial high level waste (HLW) and which at the same time, has a higher leaching resistance than the currently favoured high level waste glass. The main problems arising from a product made up of different phases, each of them taking up a certain fraction of the HLW-elements into solid solution, are1) the necessity of very intimate mixing of the HLW-elements and the inert additives because otherwise undesired highly leachable phases might be formed;2) the detrimental effect transmutation of the radioactive elements will most probably have on the crystal structure in which they are present. Fracturing and loss of the low solubility of the products are likely to occur.

Publisher

Springer Science and Business Media LLC

Subject

General Engineering

Reference5 articles.

1. 3. Dix S. , in:Proceedings of the International Seminar on Chemistry and Process Engineering for High-Level Liquid Waste Solidification, Jül-Conf.-42 (1981).

2. Dissolution of Aluminum-, Titanium-, and Zirconium-Based Crystalline Waste Form Components Under Hydrothermal Conditions

3. Evaluation of Ceramic and Polymeric Materials for Use in Engineered Barrier Systems

4. 4. Ringwood A.E. : Immobilization of High Level Nuclear Reactor Wastes in Synroc, Publ. No. 1475, Research School of Eath Sciences, Australian National University (1981)

5. Titanate Waste Forms for High Level Waste — An Evaluation of Materials and Processes

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