Stability of CsCl-type intermetallic compounds under ball milling

Abstract

We investigated the stability of the CsCl-type compounds AlRu, SiRu, NiTi, and CuEr under heavy deformation by high-energy ball milling. As a result, nanocrystalline intermetallic compounds have been synthesized with a microstructure showing a mixture of highly strained crystallites (5–12 nm) with random orientation. Thermal analysis of the samples indicates stored deformation energies of 5–10 kJ/mole stored by incorporation of lattice defects, chemical disorder and grain boundaries, and an increase of the heat capacity of up to 13%. Chemical disordering of the crystal is monitored by means of the long-range order parameter. The observed decrease in chemical order can be explained by the high grain boundary density of nanocrystalline metals.