Precursor Chemistry and the Structure of Silica Aerogels

Abstract

ABSTRACTSmall-angle X-ray scattering is used to characterize the structure of aerogels prepared by two-stage polymerization processes. Second-stage catalysis controls the resistance to collapse during drying with the base-catalyzed system being most resistant. Base catalysis in the second stage leads to compaction of the polymer network on short length scales. This short-scale rigidity makes the networks sufficiently robust to withstand the surface tension forces present during solvent extraction and re-exposure to the atmosphere. Aging in solution also improves aerogel quality. In this case, a dissolution-repolymerization process leads to short length scale circuits and improved rigidity.