Effect of Doping with Nitrogen and Boron on Cathodoluminescence of CVD-Diamond

Author:

Yokota Y.,Kawarada H.,Hiraki A.

Abstract

ABSTRACTWe have investigated cathodoluminescence (CL) of nitrogen- and boron-doped CVD diamonds compared with type Ib and undoped CVD diamonds. The CL spectrum of nitrogen-doped CVD diamond shows some luminescent centers, which are not observed in undoped one. Especially 2.15 eV (575 nm) and 1.67 eV (GRl) centers are prominent. CVD diamond doped with both nitrogen and boron shows a similar CL spectrum to boron-doped CVD diamond at lower concentration of nitrogen, and shows a spectrum composed of the centers obtained by nitrogen-doping and by boron-doping at higher concentration of nitrogen. Highenergy electron irradiation to nitrogen-doped CVD diamond produces an intense luminescent center having a zero-phonon line at 3.19 eV, and the following annealing make the emission of 2.15 eV center much more intense.

Publisher

Springer Science and Business Media LLC

Subject

General Engineering

Reference14 articles.

1. [11] Kawarada H. , Yokota Y. , Mori Y. , Nishimura K. and Hiraki A. , J. Appl. Phys. 66 (in press).

2. Diamond synthesis from gas phase in microwave plasma

3. Blue and Green Cathodoluminescence of Synthesized Diamond Films Formed by Plasma-Assisted Chemical Vapour Deposition

4. [14] Nishida Y. , Mita Y , Mori K. , Okuda S. , Sato S. , Yazu S. , Nakagawa M. and Okada M. , Proc. 15th Intern. Conf. on Defects in Semicond. Budapest, 1988 (Trans-Tech Pub. Switzenland).

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