Sol-gel preparation of amorphous ZBLA heavy metal fluoride powders

Author:

Melling Peter J.,Thomson Mary A.

Abstract

Amorphous fluoride powder in the ZrF4-BaF2-LaF3-AlF3 (ZBLA) system has been prepared by a direct chemical route from metal alkoxides by reaction with bromine trifluoride. The potential of bromine trifluoride as a solvent for use in sol-gel synthesis of fluoride glass is discussed.

Publisher

Springer Science and Business Media LLC

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference10 articles.

1. Nucleation as a Function of Temperature in the ZrF4 - BaF2 Glass Forming Systems around Tg

2. 7 Sarhangi A. , ibid., 293–302.

3. 6 France P.W. , Carter S. F. , Moore M.W. , and Williams J. R. , ibid., 253–264.

4. 3 Robinson M. , ibid., 11–25.

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