Shelf-life of uranium oxide microparticle reference materials and possible implications for the identification of optimal storage conditions

Abstract

AbstractDuring their inspections of nuclear facilities, inspectors of the International Atomic Energy Agency (IAEA) collect environmental swipe samples containing uranium dust particles. As reference materials, well-characterized uranium microparticles are required that are suitable for quality control, analytical refinement and method development tasks. At Forschungszentrum Jülich (FZJ), uranium oxide reference microparticles are produced using an aerosol-based process. A core requirement for distribution of a potential reference material is to guarantee a practical shelf-life. Previous studies of structure and shape of uranium oxide microparticles demonstrated possible alteration leading to the formation of uranium hydroxides such as schoepite. A systematic shelf-life study exploring storage under different environmental conditions was launched in late 2021. Uranium microparticles were stored in three environments simulating potential long-term storage conditions, whereas a fourth experiment used an unrealistically harsh environment to assess the effects of accelerated alteration. At the time of writing, only the uranium microparticles intentionally stored under these extreme conditions have shown significant signs of alteration. This implies that synthetic uranium oxide microparticles under common storage conditions have minimal shelf-lives of at least 1 year, and likely much longer. Graphical abstract