Exposure of Diamond to Atomic Hydrogen: Secondary Electron Emission and Conductivity Effects

Author:

Malta D. P.,Posthill J. B.,Humphreys T. P.,Thomas R. E.,Fountain G. G.,Rudder R. A.,Hudson G. C.,Mantini M. J.,Markunas R. J.

Abstract

ABSTRACTSecondary electron (SE) yield was enhanced by a factor of ∼30 and surface conductance increased up to 10 orders of magnitude when O-terminated or non-terminated natural diamond (100) surfaces were exposed to atomic H. The SE yield from atomic H-exposed surfaces was spatially dependent on near-surface microcrystalline perfection enabling defect-contrast imaging in the conventional SE mode of the scanning electron microscope (SEM). Ultraviolet photoelectron spectroscopy (UPS) on atomic H-exposed surfaces revealed an intense low energy peak attributed to photoexcitation of secondary electrons into unoccupied hydrogen-induced states near the conduction band edge and their subsequent escape into vacuum. The low energy photoemission peak, enhanced SE yield and enhanced surface conductivity were completely removed via high temperature annealing or exposure to atomic O creating the denuded or O-terminated surfaces, respectively.

Publisher

Springer Science and Business Media LLC

Subject

General Engineering

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