Composition and Morphology of Luminescent Porous Si

Abstract

ABSTRACTUsing thermal effusion of H together with a weighing of the remaining Si we determine the composition of luminescing porous Si. From studies of the IR vibration spectrum and its change with effusion we. argue that the H of freshly prepared microporous Si is bound in the dihydride form SiH2. We thus obtain a surface to volume ratio and a characterisicic linear dimension of the porous surface layer. The paper concludes with some observations on photo- and electroluminescence.