Interaction of Alkalis (CS+) With Calcium Silicates Hydrates

Abstract

ABSTRACTC-S-H of different Ca/Si ratios were synthesized in suspension. Cesium chloride (0.5 M) was put in contact with these C-S-H in reactors for 30 days at 25 °C with solution/solid ratios of 50. The quantities of cesium fixed by the C-S-H was determined by microanalyses and the mechanisms of retention in relation with the C-S-H structure was investigated by 133Cs Nuclear Magnetic Resonance (NMR). The influence of the humidity yield in which the C-S-H were stored was also studied.At 100% of humidity, some cesium ions are trapped in the pore network of the C-S-H. However, most cesium ions are incorporated in the hydrated interlayers of the C-S-H between the silica chains of the structure. They are mobile in this interlayer space. At high Ca/Si ratio, the charge of incorporated Cs+ ions in the structure should be compensated by the associated Cl- incorporation. At low Ca/Si, the presence of silanol groups in the C-S-H structure, which becomes closer to that of tobermorite (Ca/Si about 0.8), makes possible the exchange or substitution H'<->Cs'. The resulting retention of cesium in the C-S-H then becomes higher.