Melt Diffusion in Model Liquid Crystalline Polyiers

Author:

Hall E.,Ober C.K.,Kramer E.J.,Colby R.H.,Gillmor J.R.,Galli G.

Abstract

AbstractDiffusion of model main-chain and side-chain liquid crystalline polymers was studied in the nematic phase. The concentration of deuterium labeled polymer vs. depth in a thick matrix layer was profiled with Forward Recoil Spectrometry to determine diffusion coefficients. In each system, the tracer diffusion coefficient was measured as a function of temperature, and correlated both with phase transitions determined by thermal analysis and with melt viscosity data.

Publisher

Springer Science and Business Media LLC

Subject

General Engineering

Cited by 4 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Main Chain Order and Dynamics in a Liquid Crystalline Side-Group Polymer;Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals;1995-06

2. Nematic-smectic biphase of a main-chain liquid crystalline polyether;Journal of Materials Science;1995-04

3. Linear viscoelasticity of side chain liquid crystal polymer;Liquid Crystals;1993-02

4. The temperature dependence of nematic liquid crystalline polymer melt diffusion;Liquid Crystals;1993-01

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