Hierarchy in Extended Chain Polymers

Author:

Klunzinger P. E.,Eby R. K.,Adams W. W.

Abstract

AbstractRigid rod polymers are of potential use in fibers for composites because of their high specific tensile strength and modulus as well as their high thermal stability. Some other common properties of systems meeting these criteria are a nonlinear elasticity (increasing Young's modulus with increasing tensile stress) and a negative coefficient of thermal expansion along the fiber axis. In composites, these two properties can combine to cause an increase of Young's modulus with increasing temperature and can lead to yielding or interfacial failure. The source of the nonlinear elasticity resides at two length scales: 1) the scale of the crystallites, (the reversible realignment of the crystallites along the fiber axis with increasing stress), and 2) at the scale of the molecules, (an inherent nonlinear elasticity of the molecules themselves). The former effect is reviewed and computational results for the latter are presented along with computational results for the molecular origin of the negative coefficient of thermal expansion.

Publisher

Springer Science and Business Media LLC

Subject

General Engineering

Reference39 articles.

1. 36. Sheaffer P. M. , in Proceeding and Program of Carbon 1987, edited by Thrower P.A. , (American Carbon Society 1987). pp. 20–21.

2. 31. Reference 5 lists data for P-25,P-55,P-75,P-100 and p-120. The nonlinear elasticity of P-25 is not included in Table 1. The large observed NLE at 23 °C (97 GPa at a stress of 0.11 MPa) less the predicted NLE (44 GPa at the same stress) yields a residual NLE of 53 GPa. This suggests that a third mechanism might be operating in this sample. The increase of the NLE of P-55 and P-75 with temperature is consistent with this hypothesis. That for P-55 approaches that of P-25 at 210 0 C and that for P-75 has increased considerably at 450°C1,5,18,19. Thus, there might be another mechanism of NLE which is a function of temperature as well as some of the parameters which vary with fiber processing (crystal size, orientation, perfection, c dimension, etc). For example motion and pinning of basal dislocations have been considered11,32,33. The modulus given in the last two references is observed to increase in the same temperature range as that for the pitch-based fibers in the present work1,5,14,15. The results for P-120 are not included in Table 1 because all the experimental errors would make the uncertainty of the residual value to be used for column three too large.

3. Calculation of polymer elastic moduli using semiempirical methods

Cited by 1 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Rigid-Rod Polymers;Encyclopedia of Polymer Science and Technology;2002-07-15

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