Thermodynamics of solid and liquid aluminium

Author:

Marukovich E. I.1,Stetsenko V. Yu.1,Stetsenko A. V.2

Affiliation:

1. Institute of Technology of Metals of National Academy of Sciences of Belarus

2. Belarusian‑Russian University

Abstract

Based on thermodynamic calculations, it is shown that in the temperature range of 298–1273 K, heating and cooling of aluminum are thermodynamically equilibrium processes. When aluminum is heated, the molar volume energy of Gibbs decreases and the molar boundary energy of nanocrystals increases. When aluminum is cooled, the molar volume energy of Gibbs increases and the molar boundary energy of nanocrystals decreases. Liquid aluminum is a nanostructured system. Dendritic microcrystals are formed from nanocrystals. They play a large role in the processes of changing the structure of aluminum during its heating and cooling.

Publisher

Belarusian National Technical University

Subject

Pulmonary and Respiratory Medicine,Pediatrics, Perinatology, and Child Health

Cited by 3 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Current state of metal melt crystallization theory. Foundry production and metallurgy;Litiyo i Metallurgiya (FOUNDRY PRODUCTION AND METALLURGY);2022-03-12

2. Calculation of parameters of elementary nanocrystals of liquid metals at melting temperature;Litiyo i Metallurgiya (FOUNDRY PRODUCTION AND METALLURGY);2021-12-20

3. Calculation of thermodynamic parameters of metals;Litiyo i Metallurgiya (FOUNDRY PRODUCTION AND METALLURGY);2021-12-20

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