Investigation of the viable role of oil sludge-derived activated carbon for oily wastewater remediation

Abstract

A wide range of studies has been carried out to describe the equilibrium data of adsorption for the surface adsorption process. However, no extensive investigation has been carried out to evaluate the oil sludge based activated carbon surface adsorption. Therefore, the possibility of carbon active production using different oil sludges and consequently the adsorption mechanism of these kind of adsorbents is still unknown. In this study, a novel low-cost approach was introduced to synthesize the activated carbon using oil sludge applying a two-step process including carbonization and chemical activation. In this way, four different types of oil sludges were characterized and then applied to synthesize different carbon actives and their performance were investigated as an adsorbent. The results showed that all synthesized activated carbons, with about 6% ash and pH = 7 and the specific surface area of 110 m2/gr, have the ability to treatment of oily wastewater; which can be referred to the high carbon content (>80%). The iodine number and the efficiency of prepared activated carbon were obtained as 406.8 mg/g and 94%, respectively. The adsorption process was also studied at different process conditions such as temperature (308–338 K), pH value (3–9) and adsorbent amount (50–200 mg/L) to find the optimum condition for wastewater treatment. The results show that the pH value has an optimum in the adsorption rate (the maximum adsorption was measured at pH = 5) and the adsorption capacity can be reduced by increasing the temperature or decreasing the adsorbent amount. Moreover, three different adsorption isotherm models were applied, i.e., Langmuir, Temkin, and Freundlich isotherms; which the Langmuir equation was more suitable than others investigated isotherm models with R2 ≈ 0.999.