A straightforward approach utilizing an exponential model to compensate for turbidity in chemical oxygen demand measurements using UV-vis spectrometry

Abstract

Recently, ultraviolet-visible (UV-vis) absorption spectrometry has garnered considerable attention because it enables real-time and unpolluted detection of chemical oxygen demand (COD) and plays a crucial role in the early warning of emerging organic contaminants. However, the accuracy of detection is inevitably constrained by the co-absorption of organic pollutants and turbidity at UV wavelengths. To ensure accurate detection of COD, it is necessary to directly subtract the absorbance caused by turbidity from the overlaid spectrum using the principle of superposition. The absorbance of COD is confined to the UV range, whereas that of turbidity extends across the entire UV-vis spectrum. Therefore, based on its visible absorbance, the UV absorbance of turbidity can be predicted. In this way, the compensation for turbidity is achieved by subtracting the predicted absorbance from the overlaid spectrum. Herein, a straightforward yet robust exponential model was employed based on this principle to predict the corresponding absorbance of turbidity at UV wavelengths. The model was used to analyze the overlaid absorption spectra of synthetic water samples containing COD and turbidity. The partial least squares (PLS) method was employed to predict the COD concentrations in synthetic water samples based on the compensated spectra, and the corresponding root mean square error (RMSE) values were recorded. The results indicated that the processed spectra yielded a considerably lower RMSE value (9.51) than the unprocessed spectra (29.9). Furthermore, the exponential model outperformed existing turbidity compensation models, including the Lambert-Beer law-based model (RMSE = 12.53) and multiple-scattering cluster method (RMSE = 79.34). Several wastewater samples were also analyzed to evaluate the applicability of the exponential model to natural water. UV analysis yielded undesirable results owing to filtration procedures. However, the consistency between the compensated spectra and filtered wastewater samples in the visible range demonstrated that the model is applicable to natural water. Therefore, this proposed method is advantageous for improving the accuracy of COD measurement in turbid water.