Abstract
Photoelectron spectroscopy is applied to investigate electronic structure and electron dynamics in outer and inner shells of atoms, molecules and clusters in the gas phase.he article presents threshold photoelectron spectroscopy is presented, in which photoelectrons with near zero kinetic energy are detected. It is illustrated by describing the photoelectron spectra of nitrogen and furan obtained in the measurements using synchrotron radiation. These spectra show significant contributions of the autoionizing states to the processes of threshold photoionization.
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