Abstract
Recently, nickel phosphides (Ni-P) in an amorphous state have emerged as potential catalysts with high intrinsic activity and excellent electrochemical stability for hydrogen evolution reactions (HER). However, it still lacks a good strategy to prepare amorphous Ni-P with rich surface defects or structural boundaries, and it is also hard to construct a porous Ni-P layer with favorable electron transport and gas–liquid transport. Herein, an integrated porous electrode consisting of amorphous Ni-P and a Ni interlayer was successfully constructed on a 316L stainless steel felt (denoted as Ni-P/Ni-316L). The results demonstrated that the pH of the plating solution significantly affected the grain size, pore size and distribution, and roughness of the cell-like particle surface of the amorphous Ni-P layer. The Ni-P/Ni-316L prepared at pH = 3 presented the richest surface defects or structural boundaries as well as porous structure. As expected, the as-developed Ni-P/Ni-316L demonstrated the best kinetics, with η10 of 73 mV and a Tafel slope of ca. 52 mV dec-1 for the HER among all the electrocatalysts prepared at various pH values. Furthermore, the Ni-P/Ni-316L exhibited comparable electrocatalytic HER performance and better durability than the commercial Pt (20 wt%)/C in a real water electrolysis cell, indicating that the non-precious metal-based Ni-P/Ni-316L is promising for large-scale processing and practical use.
Funder
National Natural Science Foundation of China
Fundamental Research Funds for the Central Universities
Communication Program for Young Scientist in USTB
Subject
General Materials Science,General Chemical Engineering
Cited by
3 articles.
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