Gel Diffusiophoresis of a Spherical Colloidal Particle

Abstract

A theoretical framework is established for the gel diffusiophoresis of a spherical colloidal particle moving through an uncharged dilute porous polymer gel medium when an electrolyte concentration gradient field is applied. The network of cross-linked polymer segments is treated as a porous skeleton containing an electrolyte solution using the Brinkman–Debye–Bueche model. We derive a general expression for the gel-diffusiophoretic mobility of a charged spherical colloidal particle. Based on this general mobility expression, we farther derive a closed-form approximate expression for the gel-diffusiophoretic mobility of a weakly charged spherical particle correct to the second order of the particle’s zeta potential. The obtained mobility expression depends on the Debye–Hückel parameter and the Brinkmann parameter.