Embedded Graphite and Carbon Nanofibers in a Polyurethane Matrix Used as Anodes in Microbial Fuel Cells for Wastewater Treatment

Author:

Pérez-Rodríguez Pedro1ORCID,Covarrubias-Gordillo Carlos A.2,Rodríguez-De la Garza José A.3ORCID,Barrera-Martínez Cynthia L.4ORCID,Martínez-Amador Silvia Y.5

Affiliation:

1. Departamento de Ciencias del Suelo, Universidad Autónoma Agraria Antonio Narro, Calzada Antonio Narro 1923, Buenavista, Saltillo 25315, Coahuila, Mexico

2. Departamento de Materiales Avanzados, Centro de Investigación en Química Aplicada, Boulevard Enrique Reyna Hermosillo 140, San José de los Cerritos, Saltillo 25113, Coahuila, Mexico

3. Departamento de Biotecnología, Facultad de Ciencias Químicas, Universidad Autónoma de Coahuila, José Cárdenas Valdez y Venustiano Carranza S/N, Colonia República Oriente, Saltillo 25280, Coahuila, Mexico

4. Centro de Investigación para la Conservación de la Biodiversidad y Ecología de Coahuila, Universidad Autónoma de Coahuila, Miguel Hidalgo 212, Zona Centro, Cuatrociénegas 27640, Coahuila, Mexico

5. Departamento de Botánica, Universidad Autónoma Agraria Antonio Narro, Calzada Antonio Narro 1923, Buenavista, Saltillo 25315, Coahuila, Mexico

Abstract

Composites of polyurethane and graphite and polyurethane and carbon nanofibers (PU/Graphite 0.5% and PU/CNF 1%) were synthesized and used as anodes in dual-compartment microbial fuel cells (MFCs) for municipal wastewater treatment; electrical energy generation and organic matter removal were assessed. The maximum power density, coulombic efficiency and chemical oxygen demand (COD) removal efficiency in the MFCs packed with the PU/Graphite 0.5% and PU/CNF 1% composites were 232.32 mW/m3 and 90.78 mW/m3, 5.87 and 4.41%, and 51.38 and 68.62%, respectively. In addition, the internal resistance of the MFCs with the best bioelectrochemical performance (PU/Graphite 0.5%) was 1051.11 Ω. The results obtained in this study demonstrate the feasibility of using these types of materials in dual-compartment MFCs for wastewater treatment with electric power generation.

Publisher

MDPI AG

Subject

Polymers and Plastics,General Chemistry

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